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In the title compound, [RuCl(C 6 H 6 )(C 15 H 17 NS)]PF 6 , the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η 6 -benzene ligand, a chloride ligand and a 2-[2-( tert -butyl­sulfan­yl)phen­yl]pyridine (btppy) ligand. The btppy ligand acts as a  N , S -bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S—Ru—N bite angle is 86.76 (9)°, and the dihedral angle between the pyridine and benzene rings in btppy is 39.8 (2)°. The unit cell contains two pairs of racemic diastereomers with ( SRu , SS ) and ( RRu , RS ) configurations, in which the  tert -butyl group on the coordin­ated S atom is distant from the η 6 -benzene ligand.

(η6-Benzene){2-[2-(tert-butylsulfanyl)phenyl]pyridine-κ2N,S}chloridoruthenium(II) hexafluoridophosphate

(η⁶-Benzene){2-[2-(tert-butylsulfanyl)phenyl]pyridine-κ²N,S}chloridoruthenium(II) hexafluoridophosphate