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The title compound, [Ag 2 (NCS) 2 (C 14 H 38 B 10 P 2 ) 2 ], was synthesized by the reaction of 1,2-bis­(diiso­propyl­phos­phan­yl)-1,2-dicarba- closo -dodeca­borane with AgSCN. The diisopropyl­phosphanyl- closo -carborane ligand is coordinated in a bidentate manner to the Ag I  atom through the two P atoms. The coordination of the Ag I  atom is distorted tetra­hedral, in which two vertices are formed by the P atoms of the chelating diphosphine ligand, and the other two are occupied by the S and N atoms of the two bridging thio­cyanate anions, leading to a centrosymmetric binuclear complex. The distance between the two C atoms in the carborane skeleton is 1.851 (6) Å.

Di-μ-thiocyanato-bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane]silver(I)}