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In the title complex, [CdCl 2 (C 4 H 8 O 2 )]  n  , two different  Cd II  ions are present, one in a general position and one with site symmetry 2. The Cd II  ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa­hedral geometry and is connected to neighboring Cd II  ions by two bridging chloride anions, generating infinite linear chains along the  a  axis. These chains are further inter­connected by bridging 1,4-dioxane ligands, affording a three-dimensional network.

Poly[di-μ2-chlorido-μ2-(1,4-dioxane-κ2O:O′)-cadmium(II)]

Poly[di-μ₂-chlorido-μ₂-(1,4-dioxane-κ²O:O′)-cadmium(II)]