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The title compound, [Zn(C 6 H 4 N 5 ) 2 (H 2 O) 4 ]·4H 2 O, was synthesized by the hydro­thermal reaction of Zn(CH 3 COO) 2 ·2H 2 O with 3-(2 H -tetra­zol-5-yl)pyridine. The Zn II  ion is located on an inversion center and is coordinated by two pyridine N atoms from two 5-(3-pyrid­yl)tetra­zolide ligands and four coordinated water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the pyridine and tetra­zole rings is 9.920 (7)°. In the crystal, mol­ecules are linked into a three-dimensional network by inter­molecular O—H⋯O and O—H⋯N hydrogen bonds involving the tetra­zole group N atoms, the aqua ligands and solvent water mol­ecules.

Tetraaquabis[5-(3-pyridyl)tetrazolido-κN5]zinc(II) tetrahydrate

Tetraaquabis[5-(3-pyridyl)tetrazolido-κN⁵]zinc(II) tetrahydrate