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The reaction of 2-acetylpyridine with silver(I) tetra­fluorido­borate leads to the discrete title complex, [Ag(C 7 H 7 NO) 2 ]BF 4 , in the cation of which the Ag atom is coordinated by two 2-acetylpyridine ligands, each of which is  N , O -bidentate, albeit with stronger bonding to the N atoms [Ag—N = 2.2018 (15) and 2.2088 (14) Å; Ag—O = 2.5380 (13) and 2.5454 (13) Å]. The four-coordinate Ag atom has a seesaw coordination geometry with a τ 4  index of 0.51. The tetra­fluoridoborate anion is disordered over two orientations with 0.568 (10):0.432 (10) occupancies.

Bis(2-acetylpyridine-κ2N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry

Bis(2-acetylpyridine-κ²N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry