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In the title complex, [Cu(C 14 H 14 NO 2 ) 2 ], the discrete complex mol­ecules have crystallographic inversion symmetry. The slightly distorted square-planar coordination sphere of the Cu II  atom comprises two phenolate O atoms and two oxime N atoms from two bidentate–chelate 2-[1-(eth­oxy­imino)­eth­yl]-1-naphtho­late  O -ethyl oxime ( L− ) ligands [Cu—O = 1.8919 (17) Å and Cu—N = 1.988 (2) Å]. The two naphthalene ring systems in the mol­ecule are parallel, with a perpendicular inter­planar spacing of 1.473 (2) Å, while each complex unit forms links to four other mol­ecules  via  inter­molecular methyl C—H⋯π inter­actions, giving an infinite cross-linked layered supra­molecular structure

Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ2N,O1}copper(II)

Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ²N,O¹}copper(II)