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In the title complex, [Co(C 6 H 14 NO 3 )(N 3 )] or [Co(teaH 2 )N 3 ], the Co II  atom resides in a trigonal–bipymidal O 3 N 2  environment formed by three O atoms and one N atom from a simply deprotonated tetra­dentate triethano­lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O—H⋯O hydrogen-bonding inter­actions between the ethanol OH groups and the ethano­late O atom of a neighbouring complex into chains running parallel to [010].

Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ4N,O,O′,O′′}cobalt(II)

Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ⁴N,O,O′,O′′}cobalt(II)