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The title salt, C 14 H 16 N 42+ ·2C 14 H 9 O 4 S 2− ·2H 2 O, was obtained by the co-crystalization of 2,2′-dithio­dibenzoic acid with 1,4-bis­(imidazol-1-ylmeth­yl)benzene. It consists of 2-[(2-carb­oxy­phen­yl)disulfan­yl]benzoate anions, centrosymmetric 1,1′-( p -phenyl­enedimethyl­idene)diimidazol-3-ium cations and water mol­ecules. O—H⋯O, O—H⋯S and N—H⋯O hydrogen-bonding inter­actions among the components lead to the formation of a three-dimensional network.

1,1′-(p-Phenylenedimethylidene)diimidazol-3-ium bis{2-[(2-carboxyphenyl)disulfanyl]benzoate} dihydrate