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In the title compound, [RuCl(C 10 H 8 N 2 )(C 6 H 12 S 3 )]NO 3 ·H 2 O or [RuCl(bpy)([9]aneS 3 )]NO 3 ·H 2 O, ([9]aneS 3  is 1,4,7-tri­thia­cyclo­nonane and bpy is 2,2′-bipyridine), the Ru II  cation has a slightly distorted octa­hedral environment composed of three facially coordinated S atoms from ([9]aneS 3 ), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water mol­ecule of crystallization are engaged in O—H⋯O hydrogen-bonding inter­actions, leading to a supra­molecular chain running parallel to the  c  axis.

acta crystallographica. section e

(2,2′-Bipyridine-κ2N,N′)chlorido(1,4,7-trithiacyclononane-κ3S,S′,S′′)ruthenium(II) nitrate monohydrate