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The title compound, [Ni(C 17 H 11 ClN)Cl(C 3 H 9 P) 2 ], was obtained as a product of the reaction of [Ni(PMe 3 ) 4 ] with a molar equivalent of 2,6-dichloro- N -naphthyl­benzaldehyde­amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni II  atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in  trans  positions.

trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)

trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ²C¹,N}bis(trimethylphosphane)nickel(II)