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In the title coordination polymer, [Na 2 (C 4 H 3 N 2 O 2 S)Cl(H 2 O) 2 ]  n  , the Na I  ion lies on a twofold rotation axis and the chloride anion on an inversion center. The Na I  ion is six-coordinated by two O atoms from two zwitterionic 2-mercaptopyrimidine-4,6-diolate ligands ( mm 2 symmetry), two water O atoms ( m  symmetry) and two Cl atoms in a distorted octa­hedral geometry. Adjacent Na I  ions are bridged by an olate group, a water mol­ecule and a chloride anion into a three-dimensional network. The crystal structure is further stabil­ized by N—H⋯Cl, O—H⋯O and O—H⋯S hydrogen bonds.

acta crystallographica. section e

Poly[di-μ2-aqua-μ4-chlorido-μ4-(2-mercaptopyrimidine-4,6-diolato-κ4O:O:O′:O′)-disodium(I)]