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The asymmetric unit of the title complex, [Cu(C 14 H 17 NO 4 )(C 12 H 8 N 2 )]·H 2 O, contains two independent Cu II  complex mol­ecules and two uncoordinated water mol­ecules. In each complex mol­ecule, the Cu atom is  O , N , O ′-chelated by the tridentate Schiff base ligand and  N , N ′-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu—N bond distances in the apical directions are 2.298 (4) and 2.268 (4) Å. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds together with C—H⋯π inter­actions result in a three-dimensional supra­molecular structure.

acta crystallographica. section e

[N-(3-Methoxy-2-oxidobenzylidene-κO2)leucinato-κ2N,O](1,10-phenanthroline-κ2N,N′)copper(II) monohydrate