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In the title complex, {[Mn(C 14 H 6 O 6 S)(C 2 H 6 O 2 )(H 2 O) 2 ]·C 4 H 9 NO}  n  , the Mn II  ion is six-coordinated in a  trans -octa­hedral geometry by two carboxyl­ate O atoms from two 5,5-dioxodibenzo[ b , d ]thio­phene-3,7-dicarboxyl­ate ( L ) ligands in a monodentate mode, two O atoms from two ethyl­ene glycol (EG) mol­ecules and two aqua O atoms. The metal ions are linked by the EG and  L  ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O—H⋯O hydrogen bonds.

acta crystallographica. section e

Poly[[diaqua(μ2-5,5-dioxodibenzo[b,d]thiophene-3,7-dicarboxylato)(μ2-ethylene glycol)manganese(II)] dimethylacetamide solvate]