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The title compound, C 15 H 17 ClNO 2 S + ·C 10 H 15 O 4 S − ·C 3 H 6 O, was synthesized by  N -alkyl­ation of α-amino-(2-chloro­phen­yl)acetate with 2-thienylethyl  p -toluene­sulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H⋯O hydrogen bonds. The thio­phene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4).

(R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate