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In the title compound, [ReBr(C 12 H 9 ClN 2 )(CO) 3 ], the Re I  atom has a distorted octa­hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa­hedron is due to a small bite angle of the chelating bidentate diimine ligand [N—Re—N = 75.3 (3)°].

Bromidotricarbonyl[4-chloro-N-(2-pyridylmethylidene)aniline-κ2N,N′]rhenium(I)

Bromidotricarbonyl[4-chloro-N-(2-pyridylmethylidene)aniline-κ²N,N′]rhenium(I)