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In the crystal structure of the title compound, C 15 H 16 N 2 O 5 S, the azomethine adopts the  E  configuration. The two heterocyclic rings adopt an anti­periplanar orientation. The mean planes of the thio­phene and furan rings are twisted by 2.51 (4)°. The crystal structure exhibits inter­molecular N—H⋯O hydrogen bonding. π–π stacking is also observed, the centroid-to-centroid distance being 3.770 (4) Å.

Diethyl 2-amino-5-[(E)-(furan-2-ylmethylidene)amino]thiophene-3,4-dicarboxylate