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The title Schiff base compound, C 18 H 14 N 2 O 3 , has an inter­mediate state between NH and OH tautomers. The mol­ecular structure is stabilized by an O—H⋯N hydrogen bond. The dihedral angle between the naphthalene ring system and the benzene ring is 37.44 (5)°.

1-[(E)-(2-Methyl-3-nitrophenyl)iminomethyl]-2-naphthol