English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The two Ni II  atoms in the title complex, [Ni 2 (CN) 4 (C 16 H 36 N 4 )]·C 3 H 7 NO·0.5H 2 O, are bridged by a cyanide ion. The macrocycle folds around one Ni II  atom, which is five-coordinated in an NiN 5  square-pyramidal geometry. The other Ni II  atom is surrounded by the cyanide ions in an NiN 4  square-planar geometry. The dimethyl­formamide solvent mol­ecule is disordered over two positions in a 0.62 (1):0.38 (1) ratio and the water mol­ecule is disordered about a center of inversion. The dinuclear mol­ecule and solvent mol­ecules are linked by N—H⋯O, N–H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional network.

acta crystallographica. section e

μ-Cyanido-1:2κ2N:C-tricyanido-2κ3C-(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1κ4N,N′,N′′,N′′′)dinickel(II)N,N-dimethylformamide monosolvate hemihydrate