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In the title complex, [Mn 3 (CH 3 CO 2 ) 6 (C 2 H 6 SO) 2 ]  n  , the Mn II  ions exhibit similar MnO 6  octa­hedral coordination geometries but with different coordination environments. One type of Mn II  ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn II  ions along the  c -axis direction, forming an infinite chain structure; the chains are further inter­connected through weak C—H⋯O and C—H⋯S hydrogen-bonding inter­actions.

Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]