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The title compound, [Cd 2 (NCS) 4 (C 8 H 8 N 2 ) 4 ], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thio­cyanate  N : S -bridges. Two 2-methyl­benzimidazole N-atom donors and one terminal thio­cyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N—H⋯S hydrogen-bonding inter­actions occur, resulting in a three-dimensional polymeric structure. The apical 2-methyl­benzimidazole ring and its symmetry-related counterpart are arranged in an anti­parallel manner with a centroid–centroid separation of 3.6050 (14) Å, indicative of a π–π inter­action.

acta crystallographica. section e

Di-μ-thiocyanato-κ2N:S;κ2S:N-bis[bis(2-methyl-1H-benzimidazole-κN3)(thiocyanato-κN)cadmium(II)]