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The title compound, [Cu(CH 3 CN)(C 12 H 12 N 2 ) 2 ](BF 4 ) 2 , crystallizes with two copper-containing cations and four tetra­fluoro­borate anions in the asymmetric unit. The structure represents a second crystal form of the salt, the first being an acetonitrile solvate [Watton (2009  ▶ ).  Acta Cryst.  E 65 , m585–m586]. The complex cation has a distorted trigonal-bipyramidal geometry, whereas the previous structure exhibits a distorted square-pyramidal geometry. One of the four BF 4−  counter-ions is disordered, with a refined site occupancy of 0.8615 (17):0.1385 (17).

Acetonitrilebis(2,9-dimethyl-1,10-phenanthroline)copper(II) bis(tetrafluoridoborate)