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In the title compound, C 12 H 24 O 4 , the dioxane ring adopts a chair conformation; the  n -hexyl chain, which occupies an equatorial position, has an extended zigzag conformation. In the crystal, mol­ecules are connected by O—H⋯O hydrogen-bonds into a zigzag chain running along the  b  axis, giving rise to a herringbone pattern.

(5-n-Hexyl-2-hydroxymethyl-1,3-dioxan-2-yl)methanol