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The title compound, Cd 2 P 4 O 12 , dicadmium  cyclo -tetra­phosphate, crystallizes isotypically with the members of the series  MII2 P 4 O 12 , where  M  = Mg, Mn, Fe, Co, Ni or Cu. Two CdO 6  octa­hedra, one with 2 and one withsymmetry, share corners with the centrosymmetric P 4 O 124−  ring anion that is built up from four corner-sharing PO 4  tetra­hedra. The isolated ring anions are arranged in layers parallel to (10    ) with the CdO 6  octa­hedra situated between these layers. The main difference between the individual  MII2 P 4 O 12  structures pertains to the different sizes of the  M O 6  octa­hedra whereas the geometric parameters of all  cyclo -P 4 O 124−  anions are very similar.

acta crystallographica. section e

Thecyclo-tetraphosphate Cd2P4O12, a member of the isotypic seriesM2P4O12(M= Mg, Mn, Fe, Co, Ni, Cu)