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In the title compound, [Co(C 10 H 12 NO 2 ) 3 ]·H 2 O, the Co III  ion is coordinated by three O atoms and three N atoms from three bidentate 2-eth­oxy-6-(methyl­imino­meth­yl)phenolate ligands in a slightly distorted octa­hedral environment. The water mol­ecule connects two ligands by O—H⋯O hydrogen bonds. One terminal methyl group is disordered over two positions, with site-occupancy factors of 0.412 (15) and 0.588 (15).

Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate

Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ²N,O¹]cobalt(III) monohydrate