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In the title rhodium(I) complex, [RhCl(C 8 H 12 )(C 5 H 12 N 2 S)],  N,N′ -diethyl­thio­urea acts as a monodenate  S -donor ligand. The rhodium(I) coordination sphere is completed by the Cl atom and the COD [= 1,5-cyclo­octa­diene] ligand inter­acting through the π-electrons of the double bonds. If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-planar coordination. The  syn  conformation of the  N,N′ -diethyl­thio­urea ligand with respect to the Cl atom is stabilized by an intra­molecular N—H⋯Cl hydrogen bond. A weak inter­molecular N—H⋯Cl inter­action links mol­ecules along the  a  axis.

Chlorido(η4-cycloocta-1,5-diene)(N,N′-diethylthiourea-κS)rhodium(I)

Chlorido(η⁴-cycloocta-1,5-diene)(N,N′-diethylthiourea-κS)rhodium(I)