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The metal atom of the title compound, [Zn(C 13 H 8 N 3 O 2 S) 2 ]·C 3 H 7 NO·H 2 O, is  O , N , O ′-chelated by two deprotonated Schiff bases and it exists in a distorted octa­hedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF mol­ecule and uncoordinated water mol­ecule engage in N—H⋯O and O—H⋯O inter­actions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio.

acta crystallographica. section e

Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ3O,N′,O′]zinc(II)N,N-dimethylformide monosolvate monohydrate