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The title compound, (C 12 H 10 BrFN)[Ni(C 3 S 5 ) 2 ], is an ion-pair complex consisting of  N -(2-fluoro-4-bromo­benz­yl)pyridinium cations and [Ni(dmit) 2 ] −  anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni III  ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal structure, weak S⋯S [3.474 (3), 3.478 (3) and 3.547 (3) Å] and S⋯π [S⋯centroid distances = 3.360 (3), 3.378 (2), 3.537 (2) and 3.681 (3) Å] inter­actions and C—H⋯F hydrogen bonds lead to a three-dimensional supra­molecular network.

1-(4-Bromo-2-fluorobenzyl)pyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III)