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In the title dinuclear salen-type complex, [CuEu(C 22 H 24 N 2 O 4 )(NO 3 ) 3 (CH 3 OH)], the Cu II  ion is five-coordinated to two imine N atoms and two phenolate O atoms and one O from the bridging nitrate group. The Eu III  ion is ligated to three nitrate groups, four O atoms from the salen-type ligand and one methanol mol­ecule, leading to a distorted tenfold coordination for the rare earth cation. One of the three nitrate anions is disordered over two positions in a 0.66 (5):0.34 (5) ratio.

{μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}methanol-μ-nitrato-dinitratocopper(II)europium(III)