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In the title complex, [PdBr(C 4 H 3 N 2 )(C 18 H 15 P) 2 ], the geometry around the Pd II  atom is distorted square-planar with the Pd II  atom displaced by 0.0150 (5) Å from the least-squares BrP 2 C plane. Two PPh 3  ligands are in  trans  positions [P—Pd—P = 176.743 (17)°], while the pyrimidinyl ligand and Br atom are  trans  to one another [C—Pd—Br = 176.56 (5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound.

trans-Bromido(pyrimidinyl-κC2)bis(triphenylphosphane-κP)palladium(II)

trans-Bromido(pyrimidinyl-κC²)bis(triphenylphosphane-κP)palladium(II)