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The asymmetric unit of the title complex, [Ni(NCS) 2 (C 13 H 20 N 2 O 2 ) 2 ], consists of two half-mol­ecules, both of which are completed by crystallographic inversion symmetry (Ni 2+  site symmetry =in both cases). Both metal ions are six-coordinated in distorted  trans -NiO 2 N 4  geometries arising from two  N , O -bidentate Schiff base ligands and two  N -bonded thio­cyanate ions. The mol­ecular conformations are reinforced by two intra­molecular N—H⋯O hydrogen bonds.

Bis{2-[3-(dimethylammonio)propyliminomethyl-κN]-6-methoxyphenolato-κO1}bis(thiocyanato-κN)nickel(II)

Bis{2-[3-(dimethylammonio)propyliminomethyl-κN]-6-methoxyphenolato-κO¹}bis(thiocyanato-κN)nickel(II)