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In the title compound, [Cu 2 Mn(C 5 HN 2 O 4 ) 2 (H 2 O) 6 ]  n  , the Cu II  ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn II  ion is coordinated by two O atoms and four water O atoms in a distorted octa­hedral geometry. Two pyrazolyl-3,5-dicarboxyl­ate anions chelate to two copper ions, forming a dinuclear unit, which further connects the Mn II  ions into chains extending along [100]. Both independent coordinated water mol­ecules on the Mn II  ion are disordered in a 50:50 fashion.

acta crystallographica. section e

catena-Poly[hexaaqua-1κO,2κO,3κ4O-(μ4-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ6O5:N1,O5′:N2,O3:O3′)(μ2-3,5-dicarboxylatopyrazol-1-ido-1:2κ4N2,O3:N1,O5)-1,2-dicopper(II)-3-manganese(II)]