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The title compound, (C 3 H 5 N 2 ) 4 [As 6 CuMo 6 O 30 ], is made up of a centrosymmetric anionic cluster and four imidazolium cations. In the cluster, the central Cu II  atom is six-coordinated and lies on an inversion center. Adjacent clusters are linked  via  N—H⋯O hydrogen bonds between the imidazole cations and polyoxidoanions into a three-dimensional supra­molecular architecture.

Tetraimidazolium hexa-μ4-oxido-dodeca-μ2-oxido-dodecaoxidohexaarsenate(III)hexamolybdenum(VI)cuprate(II)

Tetraimidazolium hexa-μ₄-oxido-dodeca-μ₂-oxido-dodecaoxidohexaarsenate(III)hexamolybdenum(VI)cuprate(II)