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The title copper(I) salt, (C 15 H 14 N 2 )[Cu(NCS) 3 ], exists as non-inter­acting cations and trigonal–planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu I  atom is displaced by 0.019 (2) Å out of the N 3  triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.

6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris(thiocyanato-κN)cuprate(I)