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In the centrosymmetric title compound, [Gd 2 (C 6 H 8 O 4 )(C 2 O 4 ) 2 (H 2 O) 2 ]  n  , the Gd 3+  cations are each coordinated by nine O atoms, three from adipate anions, two from oxalate anions and one from an aqua ligand, completing a distorted tricapped trigonal-prismatic geometry. These tricapped trigonal prisms are bridged by the adipate ligands, generating layers lying parallel to (010). The coordination polymer layers are linked into a three-dimensional framework by the rigid oxalate ligands. The adipate and oxalate ions are all located on centers of inversion. A part of the adipate anion is disordered over two positions in a 0.75:0.25 ratio.

Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)]

Poly[μ₆-adipato-diaquadi-μ₂-oxalato-digadolinium(III)]