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The Mn atom in the title compound, [Mn 2 (C 7 H 3 N 2 O 6 ) 4 (C 10 H 8 N 2 ) 2 ]  n  , is six-coordinated by two N atoms and four O atoms, forming a distorted octa­hedral geometry. The Mn—O bond lengths are in the range 2.1281 (13)–2.2011 (12) Å and the Mn—N bond lengths are 2.269 (2) and 2.278 (2) Å. Mn(II) atoms are double-bridged along the  a  axis by two pairs of bi-monodentate carboxyl groups, forming a double-stranded chain, while the bidentate 4,4′-bipyridine ligand bridges the Mn atom along the  b  axis. This results in a two-dimensional structure constructed of oblong grids with the sides of length 11.634 and 5.075 Å

A two-dimensional manganese(II) complex: poly[bis(μ2-4,4′-bipyridyl)tetrakis(μ2-3,5-dinitrobenzoato)dimanganese(II)]

A two-dimensional manganese(II) complex: poly[bis(μ₂-4,4′-bipyridyl)tetrakis(μ₂-3,5-dinitrobenzoato)dimanganese(II)]