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In the title complex, [Ni(CH 3 COO)(C 28 H 26 N 4 )]ClO 4 , the Ni II  atom is coordinated by two imine N atoms and two pyridine N atoms of the  N -[( E )-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-(2-[( E )-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl)aniline donor ligand and two O atoms of the acetate ion in a distorted octa­hedral coordination. The average Ni—N and Ni—O bond lengths are 2.131 (13) and 2.098 (11) Å, respectively. An intramolecular N—H⋯O inter­action occurs. Relatively weak inter­molecular C—H⋯O inter­actions between the ligands and the ClO 4−  ions result in a chain extending along the  b  axis.

acta crystallographica. section e

Acetato(N-[(E)-1-(6-methyl-2-pyridyl)methylidene]-2-{2-[(E)-1-(6-methyl-2-pyridyl)methylideneamino]phenethyl}aniline)nickel(II) perchlorate