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In the crystal structure of the title compound, C 14 H 16 N 4 O 22+ ·2Cl − ·CH 3 CN, weak inter­molecular N—H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic mol­ecule which is located on a centre of inversion, one chloride anion in a general position and one half acetonitrile mol­ecule which is located on a twofold axis. Because of symmetry, the C—H hydrogens of the acetonitrile solvent mol­ecule are disordered over two orientations.

6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate