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The asymmetric unit of the title organotin(IV) compound, [Sn(C 4 H 9 ) 2 (C 5 H 3 N 2 O 2 ) 2 (H 2 O)], contains one-and-a-half mol­ecules. The half-mol­ecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both mol­ecules feature seven-coordinate Sn atoms in  trans -C 2 SnN 2 O 3  penta­gonal-bipyramidal coordination environments. The carboxyl­ate anions  N , O -chelate to the Sn atom. In the crystal, the carboxyl­ate O atoms not involved in coordination serve as acceptors for O—H⋯O hydrogen bonds from adjacent water mol­ecules, generating a three-dimensional network.

Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ2N1,O)tin(IV)

Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ²N¹,O)tin(IV)