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The title complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], features a binuclear mol-ecule, which lies about a crystallographic centre of inversion; the four acetate ions each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa-hedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the tolyl ring and forms a dihedral angle of 35.34 (9)°. A bifurcated N-H⋯(O,O) hydrogen bond is present, linking the amine group to two carboxyl-ate O atoms derived from different acetate ions. In the crystal, C-H⋯π inter-actions link mol-ecules into a supra-molecular array in the bc plane.

Tetra-μ-acetato-κ8O:O′-bis{[4-methyl-N-(4-methylphenyl)pyridin-2-amine-κN1]copper(II)}

Tetra-μ-acetato-κ⁸O:O′-bis{[4-methyl-N-(4-methylphenyl)pyridin-2-amine-κN¹]copper(II)}