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The deprotonated Schiff base ligand in the title compound, [Ni(C 8 H 8 N 3 O 2 S)(C 18 H 15 P)]Cl, functions as an  N , O , S -chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hy­droxy group forms an intra­molecular O—H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the  b  axis.

acta crystallographica. section e

{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride