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Tris(2-chloro­benz­yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C 7 H 6 Cl) 3 (C 2 H 2 N 3 S)]. The asymmetric unit contains two mol­ecules which differ only in the position of the nitro­gen-bound H atom of the triazole ring; one mol­ecule is linked to the other mol­ecule by an N—H⋯N hydrogen bond. In the second mol­ecule, two of the chloro­benzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both mol­ecules shows a distorted tetra­hedral SnSC 3  coordination.

acta crystallographica. section e

Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)