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In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear mol-ecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa-hedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intra-molecular N-H⋯O hydrogen bond is present between the amino group and a carboxyl O atom. Inter-molecular inter-actions of the C-H⋯π type link mol-ecules in the crystal structure.

Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)}

Tetra-μ-acetato-κ⁸O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN¹]copper(II)}