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The tridentate Schiff base ligand of the title complex, [V(C 15 H 12 N 2 O 4 )O(C 12 H 8 N 2 )]·C 3 H 7 NO, was derived from the condensation of 2-hy­droxy-1-naphthaldehyde and  l -asparagine. The central V IV  atom is six-coordinated by one oxide O atom, two N atoms from 1,10-phenanthroline and one N atom and two O atoms from the Schiff base ligand in a distorted octa­hedral geometry. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds connect mol­ecules into centrosymmetric dimers. The C atoms of the dimethyl­formamide solvent mol­ecule are disordered over two sites with site-occupancy factors of 0.732 (13) and 0.268 (13).

acta crystallographica. section e

Oxido{N-[(2-oxido-1-naphthyl-κO)methylidene]asparaginato-κ2O1,N2}(1,10-phenanthroline-κ2N,N′)vanadium(IV)N,N-dimethylformamide monosolvate