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In the asymmetric unit of the title compound, 2C 7 H 9 ClN + ·C 9 H 6 O 42− ·2H 2 O, there are two crystallographically independent cations, one dianion and two water mol­ecules. The dihedral angle between the two carboxyl­ate groups of the dianion is 78.1 (2)°. In the crystal, the components are held together by N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming a layer parallel to the  bc  plane, with the hydro­philic and hydro­phobic groups located in the inner and outer regions of the layers, respectively.

Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate