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The title compound, [Ag(C 27 H 23 BrN 3 O 4 )(CH 3 CN) 2 ](PF 6 ) 2 , is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile mol­ecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexa­fluorido­phosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π inter­actions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], inter­molecular Ag–π inter­actions [ Cg ⋯Ag = 3.405 Å] and C—H⋯π inter­actions between pairs of adjacent mol­ecules are observed.

Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate)