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In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C-H⋯O hydrogen bonding and π-π stacking inter-actions involving the benzene rings, with a centroid-centroid distance of 3.4220 (1) Å.

Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ2N1,O)rhenate(I)

Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ²N¹,O)rhenate(I)