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The crystal structure of the title compound, C 5 H 3 BrN 2 S, shows that bromination of 1 H -thieno[2,3- d ]imidazole with  N -bromo­succinimide in acetonitrile occurs at position 5 of the bicyclic system. The mol­ecule is almost planar, with a mean deviation of 0.015 Å from the least-squares plane through all the non-H atoms. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into infinite  C (4) chains running along [101].

5-Bromo-1H-thieno[2,3-d]imidazole