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In the title compound, C 20 H 22 O 6 , the mean planes through the benzene rings make a dihedral angle of 59.82 (7)° with each other. Weak inter­molecular C—H⋯O inter­actions together with π–π stacking inter­actions [centroid–centroid distance = 3.830 (1) Å] between benzene rings are observed in the crystal packing.

Diethyl 2,2′-(biphenyl-2,2′-diyldioxy)diacetate