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In the hydro­thermally prepared title compound, [Mo 8 Zn 2 O 26 (C 8 H 7 N 3 ) 4 ]  n   or {[Zn(C 8 H 7 N 3 ) 2 ] 2 (Mo 8 O 26 )}  n  , the Zn II  atom is coordinated by two  N , N ′-bidentate 3-(2-pyrid­yl)pyrazole ligands and two O atoms from adjacent octa­molybdate polyanions, generating a distorted  cis -ZnO 2 N 4  octa­hedral geometry for the divalent metal ion. The complete octa­molbydate unit is generated by crystallographic inversion symmetry. The polyhedral connectivity leads to [100] chains in the crystal and N—H⋯O and N—H⋯(O,O) hydrogen bonds help to consolidate the packing.

Poly[(μ-β-hexacosaoxidooctamolybdato)tetrakis[3-(2-pyridyl)pyrazole]dizinc(II)]