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In the title compound, [Na(C 10 H 9 O 6 )(C 10 H 10 O 6 )]·0.5C 10 H 8 N 2 ·H 2 O, the Na atom is eight-coordinated in an distorted dicapped-octa­hedral geometry by eight O atoms from a 2-(2-carb­oxy­meth­oxy­phen­oxy)acetate ( o -BDOAH) anion and a 2,2′-( o -phenyl­enedi­oxy)diacetic acid ( o -BDOAH 2 ) mol­ecule. The uncoordinated 4,4′-bipyridine mol­ecule is arranged around an inversion center and exhibits rotational disorder. A three-dimensional supra­molecular network is built up in the crystal through O—H⋯O and O—H⋯N hydrogen bonds between the uncoordinated water mol­ecule, the uncoordinated 4,4′-bipyridine mol­ecule and the sodium complex mol­ecule.

{2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate